Tiny defects in semiconductors created ‘speed bumps’ for electrons

The new technique (left, foreground) prevents tiny defects from forming by laminating a thin sheet of metal (silver spheres) to the semiconductor layer (yellow), creating a better fit than the current process (right, background). Credit: University of California, Los Angeles

A paper about the research was published in Nature. The study was led by Xiangfeng Duan, professor of chemistry and biochemistry in the UCLA College, and Yu Huang, professor of materials science and engineering at the UCLA Samueli School of Engineering. The lead author is Yuan Liu, a UCLA postdoctoral fellow.

Their method joins a semiconductor layer and a metal electrode layer without the atomic-level defects that typically occur when other processes are used to build semiconductor-based devices. Even though those defects are minuscule, they can trap electrons traveling between the semiconductor and the adjacent metal electrodes, which makes the devices less efficient than they could be. The electrodes in semiconductor-based devices are what enable electrons to travel to and from the semiconductor; the electrons can carry computing information or energy to power a device.

Generally, metal electrodes in semiconductor devices are built using a process called physical vapor deposition. In this process, metallic materials are vaporized into atoms or atomic clusters that then condense onto the semiconductor, which can be silicon or another similar material. The metal atoms stick to the semiconductor through strong chemical bonds, eventually forming a thin film of electrodes atop the semiconductor.

One issue with that process is that the metal atoms are usually different sizes or shapes from the atoms in the semiconductor materials that they’re bonding to. As a result, the layers cannot form perfect one-to-one atomic connections, which is why small gaps or defects occur.

“It is like trying to fit one layer of Lego brand blocks onto those of a competitor brand,” Huang said. “You can force the two different blocks together, but the fit will not be perfect. With semiconductors, those imperfect chemical bonds lead to gaps where the two layers join, and those gaps could extend as defects beyond the interface and into the materials.”

Those defects trap electrons traveling across them, and the electrons need extra energy to get through those spots.

The UCLA method prevents the defects from forming, by joining a thin sheet of metal atop the semiconductor layer through a simple lamination process. And instead of using chemical bonds to hold the two components together, the new procedure uses van der Waals forces — weak electrostatic connections that are activated when atoms are very close to each other — to keep the molecules “attached” to each other. Van der Waals forces are weaker than chemical bonds, but they’re strong enough to hold the materials together because of how thin they are — each layer is around 10 nanometers thick or less.

(A nanometer is one-billionth of a meter; for comparison, a human hair is about 100,000 nanometers thick.)

“Even though they are different in their geometry, the two layers join without defects and stay in place due to the van der Waals forces,” Huang said.

Read more: Tiny defects in semiconductors created ‘speed bumps’ for electrons

thumbnail courtesy of phys.org