Mysteries of ‘magic’ angle graphene superconductors

Mysteries of ‘magic’ angle superconductors
A team led by Princeton physicist Ali Yazdani has shown that strong electron interactions play a key role in the superconductivity that has been discovered in graphene, a material made up of single-layer sheets of carbon atoms. Here, two graphene sheets stacked on each other with a twist make a long-wavelength moiré pattern. Image designed by Kai Fu for the Yazdani Lab, Princeton University

In spring 2018, the surprising discovery of superconductivity in a new material set the scientific community abuzz. Built by layering one carbon sheet atop another and twisting the top one at a “magic” angle, the material enabled electrons to flow without resistance, a trait that could dramatically boost energy efficient power transmission and usher in a host of new technologies.

Now, new experiments conducted at Princeton give hints at how this material — known as magic-angle twisted graphene — gives rise to superconductivity. In this week’s issue of the journal Nature, Princeton researchers provide firm evidence that the superconducting behavior arises from strong interactions between electrons, yielding insights into the rules that electrons follow when superconductivity emerges.

“This is one of the hottest topics in physics,” said Ali Yazdani, who is the Class of 1909 Professor of Physics and the senior author of the study. “This is a material that is incredibly simple, just two sheets of carbon that you stick one on top of the other, and it shows superconductivity.”

Exactly how superconductivity arises is a mystery that laboratories around the world are racing to solve. The field even has a name, “twistronics.”

Part of the excitement is that, compared to existing superconductors, the material is quite easy to study since it only has two layers and only one type of atom — carbon.

“The main thing about this new material is that it is a playground for all these kinds of physics that people have been thinking about for the last 40 years,” said B. Andrei Bernevig, a professor of physics specializing in theories to explain complex materials.

The superconductivity in the new material appears to work by a fundamentally different mechanism from traditional superconductors, which today are used in powerful magnets and other limited applications. This new material has similarities to copper-based, high-temperature superconductors discovered in the 1980s called cuprates. The discovery of cuprates led to the Nobel Prize in Physics in 1987.

The new material consists of two atomically thin sheets of carbon known as graphene. Also the subject of a Nobel Prize in Physics, in 2010, graphene has a flat honeycomb pattern, like a sheet of chicken wire. In March 2018, Pablo Jarillo-Herrero and his team at the Massachusetts Institute of Technology placed a second layer of graphene atop the first, then rotated the top sheet by the “magic” angle of about 1.1 degrees. This angle had been predicted earlier by physicists to cause new electron interactions, but it came as a shock when MIT scientists demonstrated superconductivity.

Seen from above, the overlapping chicken-wire patterns give a flickering effect known as “moiré,” which arises when two geometrically regular patterns overlap, and which was once popular in the fabrics and fashions of 17th- and 18th-century royals.

These moiré patterns give rise to profoundly new properties not seen in ordinary materials. Most ordinary materials fall into a spectrum from insulating to conducting. Insulators trap electrons in energy pockets or levels that keep them stuck in place, while metals contain energy states that permit electrons to flit from atom to atom. In both cases, electrons occupy different energy levels and do not interact or engage in collective behavior.

In twisted graphene, however, the physical structure of the moiré lattice creates energy states that prevent electrons from standing apart, forcing them to interact. “It is creating a condition where the electrons can’t get out of each other’s way, and instead they all have to be in similar energy levels, which is prime condition to create highly entangled states,” Yazdani said.

The question the researchers addressed was whether this entanglement has any connection with its superconductivity. Many simple metals also superconduct, but all the high-temperature superconductors discovered to date, including the cuprates, show highly entangled states caused by mutual repulsion between electrons. The strong interaction between electrons appears to be a key to achieve higher temperature superconductivity.

Read more: Mysteries of ‘magic’ angle superconductors

Image courtesy of princeton.edu

Related Links:

Harry Potter had magic. We have metamaterials.

A different spin on superconductivity—Unusual particle interactions open up new possibilities in exotic materials

Electron microscope detector achieves record resolution

A novel graphene quantum dot structure takes the cake

MOF could make plastic manufacturing more energy-efficient